Question is similar to this one: Changing the order of elements

Easier if you have unique ids, but it is possible with tag names.

(function() {
  let list = document.querySelectorAll("pre > ul > li")
  list[0].parentNode.insertBefore(list[4], list[0])
  list[0].parentNode.append(list[0]);
})();

<pre>
<ul>
<li>1</li>
<li>2</li>
<li>3</li>
<li>4</li>
<li>5</li>
</ul>
</pre>

The naive idea is to get a list of li's, then you pop the first time, then push the same item onto the list, then replace all the children.

Alternatively, Get the content of the first Li, last Li, then replace the values. The first and the second options are semantically different. One copies nodes, while the other merely copies inner text.